Yan, QiaoBanwell, MartinCoote, MichelleLee, Zhong (Richmond)Willis, Anthony2019-04-081861-4728http://hdl.handle.net/1885/159289The enantiomer, ent-4, of the true structure, 4, of the sorbicillinoid rezishanone C (sorbivinetone) has been synthesized from a homochiral cis-1,2-dihydrocatechol that is itself generated through the whole-cell biotransformation of toluene. These studies together with dispersion-corrected DFT calculations support the proposal that rezishanone C is an artefact of the isolation process and arises through a Diels-Alder reaction between ethyl vinyl ether and sorbicillinol (3).application/pdfen-AU201710.1002/asia.2017004562019-03-12