Co-ordinative activation of phosphaalkynes: Methyl neopentylidene phosphorane complexes of ruthenium(II); crystal structure of [Ru(MeP=CHBut)Cl(I)(CO)(PPh3)2]

Bedford, Robin B.Hill, Anthony F.Jones, CameronWhite, Andrew J.P.Wilton-Ely, James D.E.T.2026-01-012026-01-010300-9246WOS:A1997WF57300002ORCID:/0000-0003-2167-0604/work/181961838https://hdl.handle.net/1885/733801717The reactions of [Ru(P=CHBut)Cl(CA)(PPh3)2] (A = O or S) with iodomethane provided the phosphaalkene complexes [Ru(PMe=CHBut)Cl(I)(CA)(PPh3)2] (I trans to phosphaalkene), with one example (A = O) having been crystallographically characterised.2enCo-ordinative activation of phosphaalkynes: Methyl neopentylidene phosphorane complexes of ruthenium(II); crystal structure of [Ru(MeP=CHBut)Cl(I)(CO)(PPh3)2]1997-01-2110.1039/a607016g33748612970