The nature of species derived from [Pt(bipy) 2 ] 2+ in aqueous solution: X-ray structural, mass spectral, NMR, and computational studies

Cavigliasso, GermanStranger, RobertLo, Warrick K.C.Crowley, James D.Blackman, Allan G.2015-12-100277-5387http://hdl.handle.net/1885/62359The reaction of [Pt(bipy)2]2+ with a variety of organic and inorganic ligands in aqueous solution has been studied by 195Pt, 1H and 13C NMR, X-ray crystallography, UV-Vis spectroscopy and high-resolution mass spectrometry. 195Pt NMR spectra of D2O solutioKeywords: 195Pt NMR; Calculations; Five-coordinate; Mass spectrometry; Platinum; X-ray structureThe nature of species derived from [Pt(bipy) 2 ] 2+ in aqueous solution: X-ray structural, mass spectral, NMR, and computational studies201310.1016/j.poly.2013.05.0042016-02-24