Guimard, NathalieHo, JunmingBrandt, JosefLin, Ching-YehNamazian, MansoorMueller, Jan O.Oehlenschlaeger, KimHilf, StefanLederer, AlbenaSchmidt, Friedrich GeorgCoote, MichelleBarner-Kowollik, Christopher2015-12-132041-6520http://hdl.handle.net/1885/72945The widely accepted approach for controlling polymer debonding/rebonding properties in responsive materials has been to purposefully engineer the functional end-groups responsible for monomer dynamic bonding. Here, however, we evidence that the debondingAuthor/s retain copyrightKeywords: Building blockes; Design materials; Diels-Alder; Diels-Alder polymers; Difunctional; Polymer building blocks; Polymer systems; Responsive materials; Chemical bonds; Debonding; Entropy; Materials properties; Polymers; Chain lengthHarnessing entropy to direct the bonding/debonding of polymer systems based on reversible chemistry201310.1039/c3sc50642h2016-02-24