Synthesis, structural isomerism, and magnetism of extended framework compounds of type [Cu(dca)2(pyz)]n, Where dca = dicyanamide (N(CN)2) and pyz = pyrazine

Jensen, PaulBatten, StuartFallon, GHockless, DavidMoubaraki, BoujemaaMurray, KeithRobson, Richard2015-12-132015-12-130022-4596http://hdl.handle.net/1885/93794Two structural isomers of the dicyanamide (dca, N(CN)-2) complex [Cu(dca)2(pyz)]n (pyz = pyrazine) were prepared from aqueous solution and crystals were grown by slow diffusion and gel techniques. Crystal data: α-[Cu(dca)2(pyz)]n, CuC8H4N8, monoclinic, PKeywords: Copper(II); Dicyanamide; Extended framework; Magnetism; Pyrazine; StructureSynthesis, structural isomerism, and magnetism of extended framework compounds of type [Cu(dca)2(pyz)]n, Where dca = dicyanamide (N(CN)2) and pyz = pyrazine19992015-12-12