Gryn'ova, GannaLin, Ching-YehCoote, Michelle2015-12-130887-624Xhttp://hdl.handle.net/1885/72946The mechanism of the nitroxide mediated polymerization (NMP) is well understood, however less is known about the side-reactions that interfere and in certain cases severely compromise it. Experimental studies inevitably involve model fitting leading to atKeywords: Disproportionations; Experimental datum; Experimental studies; Kinetic simulation; Methacrylate monomers; Nitroxide mediated polymerization; Polymerization conditions; Quantum-chemical calculation; Decomposition; Equilibrium constants; Quantum chemistry;201310.1039/c3py00534h2016-02-24