Estimation of standard reduction potentials of halogen atoms and alkyl halides

Isse, Abdirisak ALin, Ching-YehCoote, MichelleGennaro, Armando2015-12-101520-6106http://hdl.handle.net/1885/58385Standard reduction potentials, SRPs, of the halogen atoms have been calculated in water on the basis of an appropriate thermochemical cycle. Using the best up-to-date thermodynamic data available in the literature, we have calculated EX/X⊖ - values of 3Keywords: Alkyl halides; Gasphase; Halogen atoms; Homolytic dissociation; Non-aqueous solvents; Pollution abatement; Standard reduction potentials; Thermochemical cycles; Thermodynamic data; Acetonitrile; Alkylation; Atoms; Bromine; Chlorine; Dimethylformamide; FreEstimation of standard reduction potentials of halogen atoms and alkyl halides201110.1021/jp109613t2016-02-24