Phang, Sieu PhengLiang, WenshengWolpensinger, BettinaKessler, Michael AndreasMacDonald, Daniel2015-12-072156-3381http://hdl.handle.net/1885/23753The suitability of using a boron-rich layer (BRL) formed during boron diffusion as a gettering layer for n-type silicon solar cells is investigated. We have studied the gettering effectiveness, generation of dislocations and associated bulk lifetime degradation, and the impact of the BRL on the saturation current density, for different thickness of BRL and postoxidation conditions. Our results show that a BRL deposited using BBr 3-based furnaces is very effective at gettering interstitial Fe, removing more than 99.9% of Fe, but that the gettered Fe is released back into the wafer when the BRL is oxidized thermally. While we have detected no significant bulk degradation due to dislocations for the diffusion conditions used, there remains a tradeoff between the gettering effect and the recombination in the boron-doped region. Although the BRL can be oxidized chemically at low temperature using boiling nitric acid without losing the gettering effect, the lowest saturation current density is obtained by means of thermal oxidation, thanks partly to a lower boron surface concentration in thermally oxidized samples.Keywords: Boron diffusions; Boron-doped; Bulk degradation; Bulk lifetime; Different thickness; Gettering; Gettering effect; Low temperatures; Post-oxidation; Saturation current; Saturation current densities; Silicon photovoltaic; Surface concentration; Surface pass Boron diffusion; emitter saturation current; impurity gettering; silicon photovoltaic cellsTradeoffs between impurity gettering, bulk degradation, and surface passivation of boron-rich layers on silicon solar cells201310.1109/JPHOTOV.2012.22263322016-02-24