Randles , MichaelLucas, NigelCifuentes, MarieSmith, MatthewWillis, AnthonySamoc, MarekHumphrey, Mark2015-12-100024-9297http://hdl.handle.net/1885/38553Molybdenum - iridium clusters Mo2Ir2{μ 4-η2-C2[(CH2) 6OH]2}(μ-CO)4(CO)4(η-C 5H4R)2 [R = H (5), Me (6), (CH 2)9O(THP) (7); THP = tetrahydropyranyl] are formed from reaction of Mo2Ir2(μ-CO)3(CO) 7(η-C5H4R)2 with the alkyne HO(CH2)6C2(CH2)6OH. ReactionKeywords: Copolymers; Molybdenum compounds; Single crystals; Size exclusion chromatography; Surface reactions; Transition metals; X ray diffraction; Diisocyanates; Fast nonlinear absorption processes; Metal clusters; Oligourethanes; Optical limiting properties; PolMixed-Metal Cluster Chemistry. 30. 1 Syntheses and Optical Limiting Properties of Cluster-Containing Oligo- and Polyurethanes200710.1021/ma07105822015-12-09