Coote, Michelle2015-12-101022-1344http://hdl.handle.net/1885/57991This article reviews recent progress in the application of quantum chemistry to radical polymerization processes, with a principle focus on establishing the current 'best-practicé methodology for obtaining chemically accurate calculations. The scope andKeywords: Ab initio; Computational chemistry; Kinetic modeling; Quantum chemical modeling; Radical polymerization; Recent progress; Atom transfer radical polymerization; Free radical polymerization200910.1002/mats.2009000502016-02-24