Waterman, SusanLee, JeanneHumphrey, Mark2015-12-130022-328Xhttp://hdl.handle.net/1885/92414Reactions of [Cp2W2Ir2(CO)10] (4) with equimolar amounts of the bidentate phosphines bis(diphenylphosphino)methane (dppm) and 1,2-bis(diphenylphosphino)ethane (dppe) afford the substitution products [Cp2W2Ir2(μ-CO)3(μ-L)(CO) 5] [L=dppm (5), dppe (6)] inKeywords: Carbonyl; Cluster; Cyclopentadienyl; Fluxionality; Iridium; Phosphine; TungstenMixed-metal cluster chemistry 15: some bidentate phosphine chemistry of tungsten-iridium clusters19992015-12-12