Usher, AlistairDalton, GulliverLucas, NigelWaterman, SusanPetrie, SimonStranger, RobertWillis, AnthonyHumphrey, Mark2015-12-132015-12-130022-328Xhttp://hdl.handle.net/1885/79513Reaction of WH(CO)3(η-C5Me5) with IrCl(CO)2(4-H2NC6H4Me) affords WIr3(μ-CO)3(CO)8 (η-C5Me5) in low yield. A structural study reveals a WIr2-centred plane of bridging carbonyls, in contrast to the crystal structure of WIr3(CO)11 (η-C5H5) (all-terminalKeywords: bridged compound; carbon monoxide; carbonyl derivative; chromium; cyclopentadiene derivative; iridium complex; ligand; molybdenum; organometallic compound; phosphine; tungsten derivative; article; calculation; carbon nuclear magnetic resonance; controlled Carbonyl; Chromium; Cluster; Crystal structure; Cyclopentadienyl; Density functional theory; Fluxionality; Iridium; Molybdenum; Tungsten200410.1016/j.jorganchem.2003.09.0262015-12-11