Garcia-Garcia, F JavierLarsson, Ann-Kristin2015-12-131293-2558http://hdl.handle.net/1885/86952The crystal structure of Ni13Sn8P3 was elucidated from High Resolution Electron Microscopy Images. It was tound to be a superstructure of the B8-type (NiAs-type) structure with Sn and P atoms ordered at the hexagonally closepacked array and Ni atoms in all octahedral and in two out of every eleven trigonal bipyramidal sites. The structure motif within a NiSn B8-type matrix comprises triangles of P atoms with two of the three edges capped by Ni atoms in trigonal bipyramidal sites. This motif is repeated along the [01̄1]B8 zone axis so that the structure can be envisaged as pairs of face-sharing Ni centered Edshammar polyhedra corner-connected along [01̄1]B8. The reciprocal lattice (H) can be described as H = G + mq1 + nq2 (where G refers to the Bragg reflections of the underlying B8-type structure, q1 = 1/11 [112̄1]B8, q2 = 1/22 [6̄515]B8 and m and n are integers. The resultant triclinic (P1̄) unit cell parameters are a = 6.456 Å, b = 21.291 Å, c = 13.247 Å, α = 81.052°, β = 56.260° and γ = 68.221°.Keywords: Crystal structure; High resolution electron microscopy; Lattice constants; Superstructure; Nickel compounds; nickel complex; phosphorus derivative; tin derivative; article; atom; chemical analysis; chemical structure; crystal structure; electron microscop B8-type structure; Crystal structure; High resolution electron microscopy; Ni-Sn-P system; Ni13Sn8P3; Edshammar polyhedron; Selected area electron diffraction; Superstructure200310.1016/S1293-2558(02)00095-X2015-12-12