Hill, AnthonyManzano, Richard2020-12-142020-12-141433-7851http://hdl.handle.net/1885/217171Synthetic routes to dimetallated Cx carbon wires in which two metals are separated by a linear carbon chain involving terminal metal-carbon triple bonds are described for the complexes [(Tp*)(CO)2 W≡C-(C≡C)n -C≡W(CO)2 (Tp*)] (Tp*=hydrotris(dimethylpyrazolyl)borate) where n=1, 3 or 4, joining the previously known examples with n=0, 1 and 2 to complete the series as models for linear carbyne C∞ .DP170102695 and DP190100723application/pdfen-AU© 2019 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheimbis(carbyne)carboncarbynetungsten2019-10-2110.1002/anie.201909550