An unusual pendant-arm macrocycle formed by condensation of a cobalt(III) tripodal complex with methanal.

Angus, PatriciaGeue, RodneyJensen, NielsLarsen, KrebsQin, ChangSargeson, Alan2015-12-132015-12-131477-9226http://hdl.handle.net/1885/72556The reaction of [Co(ten)]3+ {ten = 4,4′,4″-ethylidynetris(3-thiabutan-1-amine)} with methanal and base in acetonitrile or water led to the synthesis of an unusual pendant-arm macrocyclic complex, 8-(4′-ammonio-2′-thiabutyl)-8-methyl-1-oxa-6, 10-diKeywords: Acetonitrile; Condensation; Polymers; Proteins; Synthesis (chemical); X ray crystallography; Methanal; Cobalt compoundsAn unusual pendant-arm macrocycle formed by condensation of a cobalt(III) tripodal complex with methanal.20022015-12-11