Ma, XinghuaBanwell, MartinWillis, Anthony2015-12-100163-3864http://hdl.handle.net/1885/62281The enantiomeric form, 1R, of the structure (1S) assigned to the phytotoxic natural product phomentrioloxin has been synthesized in seven steps from the homochiral cis-1,2-dihydrocatechol 3. These studies reveal that the true structure of phomentrioloxinKeywords: 1,2 dihydrocatechol; herbicide; phomentrioloxin; unclassified drug; article; chemical structure; controlled study; enantiomer; stereochemistry; synthesisChemoenzymatic total synthesis of the phytotoxic geranylcyclohexentriol (-)-phomentrioloxin201310.1021/np40028662016-02-24