A zinc(II) tetraphenylporphyrin peripherally functionalized with redox-active " trans -[(η 5 -C 5 H 5 )Fe(η 5 -C 5 H 4 )C≡C](κ 2 -dppe) 2 Ru(C≡C)-" substituents: linear electrochromism and third-order nonlinear optics

Merhi, AreejGrelaud, GuillaumeRipoche, NicholasBarlow, AdamCifuentes, MariePaul, FredericPaul-Roth, ChristineHumphrey, Mark2015-12-100277-5387http://hdl.handle.net/1885/55723A nonametallic organometallic-coordination complex (4), assembled from redox-active ferrocenyl (Fc) and Ru(κ2-dppe)2 fragments (dppe = 1,2-bis(diphenylphosphino)ethane) as peripheral donor groups and a central Zn(II) tetraphenylporphyrin (ZnTPP) core, haA zinc(II) tetraphenylporphyrin peripherally functionalized with redox-active " trans -[(η 5 -C 5 H 5 )Fe(η 5 -C 5 H 4 )C≡C](κ 2 -dppe) 2 Ru(C≡C)-" substituents: linear electrochromism and third-order nonlinear optics201510.1016/j.poly.2014.05.0132015-12-09