Henry, DavidBeckmann, AnnaliseRadom, Leo2015-12-132015-12-130004-9425http://hdl.handle.net/1885/87828A homoanomeric effect is found to stabilize the 1,2-dimethoxyethyl radical (CH3O-C•H-CH2OCH3) in a conformation in which the singly-occupied orbital at the radical centre is approximately coplanar with the p-type lone pair on the α-oxygen and with theKeywords: Chemical bonds; Conformations; Free radicals; Molecular orientation; Numerical analysis; Photoelectron spectroscopy; Dimethoxyethyl radical; Homoanomeric effect; Molecular orbital; Hydrocarbons200310.1071/CH022552023-11-26