Hill, AnthonyRae, A DavidSchultz, MadeleineWillis, Anthony2015-12-132015-12-130276-7333http://hdl.handle.net/1885/78432The diyne 4,7,10-trithiatrideca-2,11-diyne (TTDD) reacts smoothly at room temperature with [Ru(CO)2(PPh3)3] to form [Ru(CO)(PPh3) {η4-S(C2H4SCCMe)2CO-κS}], a cyclopentadienone complex in which the unique sulfur atom is also coordinated to the metal butKeywords: Atoms; Complexation; Coordination reactions; Ethers; High temperature effects; Organometallics; Ruthenium compounds; Sulfur; Cyclopentadione; Macrocyclization; Thioether; Aromatic compounds200410.1021/om03057232015-12-11