Parmar, Vijay S.Thiel, Andreas M.Nabi, RizwanGransbury, Gemma K.Norre, Marie S.Evans, PeterCorner, Sophie C.Skelton, Jonathan M.Chilton, Nicholas F.Mills, David P.Overgaard, Jacob2025-05-302025-05-301359-7345Bibtex:parmar_influence_2023https://hdl.handle.net/1885/733754670The effects of external pressure on a high-performing dysprosocenium single-molecule magnet are investigated using a combination of X-ray diffraction, magnetometry and theoretical calculations. The effective energy barrier (Ueff) decreases from ca. 1300 cm−1 at ambient pressure to ca. 1125 cm−1 at 3 GPa. Our results indicate that compression textless 1.2 GPa has a negligible effect on the Orbach process, but magnetic relaxation textgreater 1 GPa increases via Raman relaxation and/or quantum tunnelling of magnetisation.4enPublisher: The Royal Society of Chemistry2023-02-0110.1039/D2CC06722F85148671893