Lu, DiCoote, MichelleHo, JunmingKilah, NathanLin, Ching-YehSalem, GeoffreyWeir, MichelleWillis, AnthonyWild, Stanley (Bruce)Dilda, Pierre J2015-12-070276-7333http://hdl.handle.net/1885/20898The resolution and improved synthesis of the naturally occurring, adamantane-type, tetraarsenical (±)-Arsenicin A is reported. The five-step synthesis of (±)-Arsenicin A from methylenebis(phenylarsinic acid) affords (±)-Arsenicin A as air-stable, colorKeywords: Air-stable; Asymmetric unit; Chiralpak IA; Colorless crystals; Enantiomeric purity; Glioblastomas; Gold standards; High-level ab initio calculations; Inorganic oxides; Inversion center; Leukemia cells; Methylene groups; Naturally occurring; Oxygen atom; PResolution and improved synthesis of (±)-arsenicin A: a natural adamantane-type tetraarsenical possessing strong anti-acute promelocytic leukemia cell line activity201210.1021/om201180d2016-02-24