Copper(II) environments in some macrobicycle complexes at room and low temperatures: some novel binuclear chloro-bridged systems

Engelhardt, Lutz MGrondahl, LisbethHarrowfield, Jack MRalph, Stephen FSargeson, AlanSkelton, BrianSobolev, Alexandre NWhite, Allan2015-12-100923-0750http://hdl.handle.net/1885/69443Single crystal X-ray studies are recorded for five copper(II) complexes of macrobicyclic ligands. In both [Cu(sar)][ZnCl 4] (295, 170 K) determinations ('sar' = 3,6,10,13,16,19-hexaazabicyclo[6.6.6]icosane) and [Cu(NH 3) 2sar]Cl 4•6H 2O (295 K), the ligKeywords: Cage ligands; Copper(II); Crystal structure; SarcophagineCopper(II) environments in some macrobicycle complexes at room and low temperatures: some novel binuclear chloro-bridged systems201110.1007/s10847-011-9952-32016-02-24