Marshall, David LGryn'ova, GannaCoote, MichelleBarker, Philip J.Blanksby, Stephen James2015-12-101387-3806http://hdl.handle.net/1885/64313The extensive use of alkoxyamines in controlled radical polymerisation and polymer stabilisation is based on rapid cycling between the alkoxyamine (R1R2NOR3) and a stable nitroxyl radical (R1R2NO•) via homolysis of the labile OC bond. Competing homolysiExperimental evidence for competitive N-O and O-C bond homolysis in gas-phase alkoxyamines201510.1016/j.ijms.2014.06.0302015-12-10