Radical Addition to Thioketones: Computer-Aided Design of Spin Traps for Controlling Free-Radical Polymerization

Chaffey-Millar, HughIzgorodina, EkaterinaBarner-Kowollik, ChristopherCoote, Michelle2015-12-071549-9618http://hdl.handle.net/1885/17204An extensive study has been undertaken of the radical affinity of a number of thioketones (S=C(X)(Y)) with the aim of selecting combinations of X and Y that render the substrate suitable for the mediation of free radical polymerizations. Using high levelRadical Addition to Thioketones: Computer-Aided Design of Spin Traps for Controlling Free-Radical Polymerization200610.1021/ct600128t2015-12-07