Oehlenschlaeger, KimGuimard, NathalieBrandt, JosefMueller, Jan O.Lin, Ching-YehHilf, StefanLederer, AlbenaCoote, MichelleSchmidt, Friedrich GeorgBarner-Kowollik, Christopher2015-12-131759-9954http://hdl.handle.net/1885/73382A new dithioester possessing a cyano Z-group (cyano-dithioester (CDTE)) has been synthesized via a 2-step, one-pot reaction. The cyano-substituted dithioester has been found to undergo fast reversible hetero-Diels-Alder (HDA) reactions at ambient temperatKeywords: Ab initio molecular orbital calculation; Hetero-diels-Alder; On-demand systems; On-line NMR spectroscopy; One-pot reaction; Polymerization reaction; Reversible bonding; UV-vis spectroscopy; Calculations; Catalysts; Directive antennas; Experiments; NuclearFast and catalyst-free hetero-Diels-Alder chemistry for on demand cyclable bonding/debonding materials201310.1039/c3py00476g2016-02-24