Mixed-metal cluster chemistry. 24. Isocyanide derivatives of [MoIr 3 (μ-CO) 3 (CO) 8 (η-C 5 H 5 )] and [Mo 2 Ir 2 (μ-CO) 3 (CO) 7 (η-C 5 H 5 ) 2

Usher, AlistairWillis, AnthonyHumphrey, Mark2015-12-130022-328Xhttp://hdl.handle.net/1885/87677Reactions of MoIr3(μ-CO)3(CO)8 (η-C5H5) (1) with stoichiometric amounts of isocyanides afford the ligand-substituted clusters [MoIr3(μ-CO)3(CO)8-n(L)n (η-C5H5)] (L=CNBut, n=1 (3), 2 (4), 3 (5); L=CNC6H3Me2-2,6, n=1 (6), 2 (7), 3 (8)) in moderate to exKeywords: carbonyl derivative; coordination compound; cyanide; iridium complex; ligand; molybdenum complex; article; chemical reaction; cluster analysis; controlled study; crystal structure; stoichiometry; X ray analysis Carbonyl; Cluster; Cyclopentadienyl; Iridium; Isocyanide; MolybdenumMixed-metal cluster chemistry. 24. Isocyanide derivatives of [MoIr 3 (μ-CO) 3 (CO) 8 (η-C 5 H 5 )] and [Mo 2 Ir 2 (μ-CO) 3 (CO) 7 (η-C 5 H 5 ) 2200310.1016/S0022-328X(03)00438-82015-12-12