Kelly, AmyMacgregor, Stuart AWillis, AnthonyNelson, John HWenger, Eric2015-12-132015-12-130020-1693http://hdl.handle.net/1885/94246The regioselectivities of the insertion reactions of RC≡CCO2Et (R=Ph, CF3) into the aryl-palladium bond of several five-membered, ortho-palladated dimethylbenzylamine complexes, [PdCl(C6H4CH2NMe2-κC,N)] 2 (1), [PdCl(C6H4CH2NMe2-κC,N)(L)] [L=PEt3 (2),Keywords: alkyne; benzylamine derivative; carboxylic acid derivative; ester; palladium; polycyclic aromatic hydrocarbon derivative; article; carbon nuclear magnetic resonance; chemical bond; chemical reaction; chemical structure; nuclear magnetic resonance spectros Alkyne insertion; DFT calculation; Dimethylbenzylamine; NMR spectroscopy; Palladacycles; Regiochemistry200310.1016/S0020-1693(03)00149-X2015-12-12