Colebatch, AnnieHill, AnthonySharma, Manab2015-12-100276-7333http://hdl.handle.net/1885/63660The successive treatment of [W(≡CBr)(CO)<inf>2</inf>(Tp∗)] (Tp∗ = hydrotris(3,5-dimethylpyrazol-1-yl)borate) with nBuLi and ClPPh<inf>2</inf> affords the phosphinocarbyne complex [W(≡CPPh<inf>2</inf>)(CO)<inf>2</inf>(Tp∗)] (1), DFT interrogationKeywords: Carbon; Dichloromethane; Phosphorus; Sulfur; Synthesis (chemical); Tungsten; Diethyl ethers; Dimethylsulfide; Electrophiles; Electrophilic attack; Electrophilic reagents; Iodomethane; Multiple bonds; Phosphorus atom; Tungsten compounds201510.1021/om500833n2019-11-25