Dewhurst, RianHill, AnthonyWillis, Anthony2015-12-132015-12-131359-7345http://hdl.handle.net/1885/86802Fluoride mediated desilylation of the propargylidyne complex [W(≡C-C≡CSiMe3)(CO)2{HB(pz)3)] (pz = pyrazol-1-yl) in the presence of mercury(II) chloride provides the novel bis(tricarbido)complex [Hg{C≡C-C≡W(CO)2(HB(pz)3}} 2], which was structurallyKeywords: benzyl thiocyanate; dimethyl sulfoxide; hydrotrispyrazolylborate; mercury bis(tricarbido) complex; mercury chloride; mercury derivative; propargylidyne complex; unclassified drug; article; complex formation; crystal structure; desilylation; geometry; specA mercury bis(tricarbido) complex: [Hg{C≡C�C≡W(CO) 2 Tp} 2- (dmso) 4 ](dmso) 2 (Tp = hydrotrispyrazolylborate)200410.1039/b412972e2015-12-12