Zhou, XiangtingDay, AnthonyEdwards, AlisonWillis, AnthonyJackson, William Gregory2015-12-130020-1669http://hdl.handle.net/1885/82456The 1,4-bis(2-pyridylmethyl)-1,4-diazacyclononane (dmpdacn) ligand with a N4C donor set deprotonates at a CH2 γ to an amine under extraordinarily mild conditions (pH 7) and binds as a pentadentate ligand to Co(III) as the [Co(dmpdacn-C)(OH2)]2+ complex.Keywords: 1,4 bis(2 pyridylmethyl) 1,4 diazacyclononane; amine; chloride; cobalt complex; ligand; pyridine derivative; unclassified drug; article; chemical bond; drug hydroxylation; hydrolysis kinetics; nuclear magnetic resonance; oxidation; synthesis; X ray crystaFacile C-H bond activation: synthesis of the N 4 C donor set pentadentate ligand 1,4-bis(2-pyridylmethyl)-1,4-diazacyclononane (dmpdacn) and a structural study of its alkyl?cobalt(III) complex [Co(dmpdacn- C )(OH 2 )](ClO 4 ) 2 ⋅H 2 O and its hydroxylated derivative [Co(dmpdacnOH- O )Cl](ClO 4 ) 2 ⋅C 3 H 6 O200510.1021/ic040081q2015-12-11