Trinuclear mixed-valent gold complexes derived from 2-C 6 F 4 PPh 2 : phosphine oxide complexes of gold(III) and an ortho-metallated complex of gold(I)

Bennett, MartinMirzadeh, NedaossadatPriver, Steven HWagler, JorgBhargava, Suresh Kumar2015-12-100932-0776http://hdl.handle.net/1885/55908Crystals of two mixed-valent gold complexes [(O2NO)Au I(μ-2-C6F4PPh2)Au III{κ2-2-C6-F4P(O)Ph 2}(μ-2-C6F4PPh2)Au I(ONO2)] (14) and [(O2NO)AuI(μ-2- C6F4PPh2)AuIII{κ3- 2-C6F4-P(O)Ph(C6H4)}(μ-2-C 6F4PPh2)AuI] (15) have been obtained from the reaction ofKeywords: Cyclometallation; Gold; Phosphine oxide; TrinuclearTrinuclear mixed-valent gold complexes derived from 2-C 6 F 4 PPh 2 : phosphine oxide complexes of gold(III) and an ortho-metallated complex of gold(I)20092016-02-24