Green, NicholasLawrence, AndrewBojase-Moleta, GomotsangWillis, AnthonyPaddon-Row, MichaelSherburn, Michael2015-12-101433-7851http://hdl.handle.net/1885/62245Hooray Horeau! Highly enantioselective organocatalyzed Diels-Alder reaction cascades are disclosed for the first time. The reaction enables the efficient and rapid construction of enantiopure polycycles from simple achiral, acyclic polyenes.Keywords: Diels-Alder reaction; Enantiopure; Enantioselective; Polycycles; polyenes; Rapid construction; Synthetic methods; Chemical reactions; Chemistry; Cycloaddition; Hydrocarbons; Organic compounds cycloaddition; hydrocarbons; polycycles; polyenes; synthetic methods201310.1002/anie.2013021852016-02-24