Kilah, NathanWild, Stanley (Bruce)2015-12-100276-7333http://hdl.handle.net/1885/60874The first enantiomerically pure secondary iodoarsine has been prepared by ring closure of (aR)-[{Li(TMEDA)}2{2,2′-bis(methylene)-1, 1′-binaphthylyl}] with dichlorophenylarsine, followed by disproportionation of the resulting seven-membered (aR)-phenylKeywords: Absolute configuration; Air-stable; Arsenic atom; Binaphthyl; Complex cation; Diastereomers; Disproportionations; H NMR spectra; Hexafluorophosphates; Methoxymethyl; Methylene groups; NMR spectrum; P-chiral phosphines; Phosphine complex; Phosphine exchang201210.1021/om200853d2016-02-24