Cowley, Andrew RHector, Andrew LHill, AnthonyWhite, Andrew J PWilliams, DavidWilton-Ely, James2015-12-100276-7333http://hdl.handle.net/1885/50302The reactions of [RuHCl(CS)(PPh3)3] with R 1C≡CR2 (R1 = R2 = H, Ph, CO2Me; R1 = H, R2 = C6H 4Me-4; R1 = C≡CPh, R2 = Ph) lead to the five- or six-coordinate (R1 = R2 = CO2Me) σ-alkenyl complexes [Ru(CR1=CHR2)Cl(CS)(PPh 3)2], the stilbenyl derivative bKeywords: Carbon monoxide; Crystal structure; Synthesis (chemical); Thermolysis; Diphenylacetylene; Stilbenyl derivatives; Ruthenium compounds200710.1021/om700518m2015-12-09