Synthesis and resolution of ( R *, R *)-(�)-1,1,4,7,10,10-hexaphenyl-1,10-diarsa-4,7-diphosphadecane: New ligand for the stereoselective self-assembly of dicopper(I), disilver(I), and digold(I) helicates

Cook, VernonWillis, AnthonyZank, JohannWild, Stanley (Bruce)2015-12-130020-1669http://hdl.handle.net/1885/91692Diphenylvinylarsine oxide reacts with 1,2-bis (phenylphosphino)ethane in the presence of potassium tert-butoxide to give the anti-Markovnikov product (R*,R*)-(±)/(R*,R**)- 1,1,4,7,10,10-hexaphenyl-1,10-diarsa-4,7-diphosphadecane dioxide-1AsO,10AsO, whichKeywords: acetonitrile; arsine derivative; copper derivative; decane; dimethylamine; ethane; gold derivative; ligand; metal complex; oxide; palladium; phenyl group; phosphine derivative; potassium derivative; pyrophosphoric acid derivative; silver derivative; vinylSynthesis and resolution of ( R *, R *)-(�)-1,1,4,7,10,10-hexaphenyl-1,10-diarsa-4,7-diphosphadecane: New ligand for the stereoselective self-assembly of dicopper(I), disilver(I), and digold(I) helicates200210.1021/ic010988d2015-12-12