Temperature-dependent cooperative coiling of helical conformers of enantiopure oligo(tertiary phosphines)

Swiegers, GerhardWild, Stanley (Bruce)2015-12-130004-9425http://hdl.handle.net/1885/76661The specific optical rotation of an enantiopure, syndiotactic hexa(tertiary phosphine) displays a marked temperature dependence that is consistent with the cooperative formation of helically coiled conformers in solution.Keywords: Conformations; Optical rotation; Thermal effects; Conformers; Temperature dependence; OligomersTemperature-dependent cooperative coiling of helical conformers of enantiopure oligo(tertiary phosphines)200510.1071/CH052532015-12-11