Organometallic Complexes for Nonlinear Optics.XXVI Quadratic Hyperpolarizabilities of Some 4-Methoxytetrafluorophenylalkynyl Gold and Ruthenium Complexes

Hurst, StephanieLucas, NigelAsselberghs, IngeVan Boxel, RoelPersoons, Andre PierreHumphrey, Mark2015-12-132015-12-130004-9425http://hdl.handle.net/1885/92972The complexes [Au(4-C≡CC6F4OMe)(L)] [L = PMe3 (1), PPh3 (2)], trans-[Ru(4-C=CHC6F4OMe)Cl(dppm)2]PF 6 (3) and trans-[Ru(4-C≡CC6F4OMe)Cl(dppm)2] (4) have been prepared and the identity of (2) was confirmed by a structural study. Electrochemical data forOrganometallic Complexes for Nonlinear Optics.XXVI Quadratic Hyperpolarizabilities of Some 4-Methoxytetrafluorophenylalkynyl Gold and Ruthenium Complexes200110.1071/CH011082015-12-12