An organometallic tetranuclear complex of μ 4 -PO 4 : [{(Cp*Cr) 2 (μ-OMe) 2 } 2 (μ 4 -PO 4 )]X (X = I, PF 6 )

Shin, RichardTan, Geok KhengKoh, LipGoh, Lai YoongWebster, Richard2015-12-130276-7333http://hdl.handle.net/1885/82427The first discrete organometallic tetranuclear μ4-PO 4 complex, [{(Cp*Cr)2(μ-OMe)2} 2(μ4-PO4)]+ (5; Cp* = η5-C5Me5), was isolated as the iodide and PF6 salts from the reaction between NaH2PO4 and [Cp*Cr(μ-OMe)I]2 (2), which was derived from thiolateKeywords: Chemical bonds; Complexation; Coordination reactions; Crystals; Molecular structure; Phosphorus compounds; Synthesis (chemical); Metathesis; Methylation; Reaction pathways; Tetranuclear complex; OrganometallicsAn organometallic tetranuclear complex of μ 4 -PO 4 : [{(Cp*Cr) 2 (μ-OMe) 2 } 2 (μ 4 -PO 4 )]X (X = I, PF 6 )200510.1021/om048974d2015-12-11