Synthesis, reactivity, and some photochemistry of ortho-N,N-dimethylaminomethyl substituted aryl and ferrocenyl pentamethylcyclopentadienyl dicarbonyl iron complexes

Grelaud, GuillaumeRoisnel, ThierryDorcet, VincentPaul, FredericArgouarch, GillesHumphrey, Mark2015-12-100022-328Xhttp://hdl.handle.net/1885/62661Ortho-lithiated N,N-dimethylaminomethyl ferrocene and benzyldimethylamine react with Cp*Fe(CO)2I to give the new complexes ((Cp*Fe(CO)2)-2-(CH2NMe2)C5H 3)Fe(Cp) and Cp*Fe(CO)2-C6H4(o- CH2NMe2). Access to a wide variety of alkoxy-substituted complexes ((CpKeywords: Alcoholysis; Carbonyl ligand; Chelated complex; Ferrocenes; Ferrocenyl; Iron complex; Pentamethylcyclopentadienyl; Quaternization; Organometallics; Photolysis; Synthesis (chemical); Iron compounds Alcoholysis; Ferrocenes; Iron complexes; Piano-stool structuresSynthesis, reactivity, and some photochemistry of ortho-N,N-dimethylaminomethyl substituted aryl and ferrocenyl pentamethylcyclopentadienyl dicarbonyl iron complexes201310.1016/j.jorganchem.2013.05.0312016-02-24