Thiocarbamoyl complexes of ruthenium(II), rhodium(III), and iridium(III)

Hill, AnthonyTocher, DerekWhite, Andrew GWilliams, DavidWilton-Ely, James2015-12-130276-7333http://hdl.handle.net/1885/81334The reaction of [Ru(CO)2(PPh3)3] (1) or [Ru(η2-CS2)(CO)2(PPh3) 2] with N,N-dimethylthio-carbamoyl chloride provides [Ru(η2-SCNMe2)(CO)2(PPh2) 2]Cl (2·C1), thermolysis of which yields [Ru(η 2-SCNMe2)Cl(CO)(PPh2)2] (3). Treatment of 2·C1 with NaBH4 leaKeywords: Chemical analysis; Complexation; Hydrochloric acid; Iridium; Isomers; Photolysis; Rhodium; Ruthenium; Substitution reactions; Metallacyclic complexes; Thermolysis; OrganometallicsThiocarbamoyl complexes of ruthenium(II), rhodium(III), and iridium(III)200510.1021/om050514c2015-12-11