Pal, BhupenderVijayan, Bincy LathakumaryKrishnan, Syam G.Harilal, MidhunBasirun, Wan JeffreyLowe, AdrianYusoff, Mashitah M.Jose, Rajan2018-01-180925-8388http://hdl.handle.net/1885/139435Synthesis of advanced functional materials through scalable processing routes using greener approaches is essential for process and product sustainability. In this article, syntheses of nanoparticles of titanium dioxide (TiO₂), tungsten trioxide (WO₃), WO₃-doped titanium dioxide (W-TiO₂) and TiO₂/WO₃ composite at hydrothermal conditions using corresponding metal oxide precursors are described. Electrochemical charge storage capabilities of the above materials are measured using cyclic voltammetry, charge-discharge cycling and electrochemical impedance spectroscopy in aqueous KOH electrolyte. The TiO₂ and the WO₃ nanoparticle showed a specific charge (Q) of ∼12 and ∼36 mA h g⁻¹ at a current density of 2 A g⁻¹ in 6 M KOH, respectively. The Q of TiO₂ increased upon W doping up to 25 mA h g−1 for 5 wt% W-TiO2 and the WO₃/TiO₂ composite showed the highest storage capability (Q ∼40 mA h g⁻¹). Changes in the charge storage capabilities of the doped and composite materials have been correlated to materials properties.Bhupender Pal acknowledges the Research & Innovation Department of Universiti Malaysia Pahang (http://ump.edu.my) for award of Postdoctoral Fellowship. This project is funded under Flagship Strategic Leap 3 of Universiti Malaysia Pahang (Grant Number # RDU 172201).application/pdf© 2018 Elsevier B.V.Green synthesisEnergy Storage MaterialsRenewable energyBattery type electrodeSupercapacitors201810.1016/j.jallcom.2018.01.065