Lu, ZiyangNeupane, GuruJia, GuohuaZhao, HaitaoQi, DongchenDu, YapingLu, YueruiYin, Zongyou2022-07-201616-3028http://hdl.handle.net/1885/2698242D materials based on main group element compounds have recently attracted significant attention because of their rich stoichiometric ratios and structure motifs. This review focuses on the phases in various 2D binary materials including III–VI, IV–VI, V–VI, III–V, IV–V, and V–V materials. Reducing 3D materials to 2D introduces confinement and surface effects as well as stabilizes unstable 3D phases in their 2D form. Their crystal structures, stability, preparation, and applications are summarized based on theoretical predictions and experimental explorations. Moreover, various properties of 2D materials, such as ferroelectric effect, anisotropic optical and electrical properties, ultralow thermal conductivity, and topological state are discussed. Finally, a few perspectives and an outlook are given to inspire readers toward exploring 2D materials with new phases and properties.The authors gratefully acknowledge the support from the ANU Futures Scheme (Q4601024), the ANU Global Research Partnership Scheme (R468504649), ActewAGL Endowment Fund (Q4601028), and the Australian Research Council (DP190100295, LE190100014, DP180103238), the National Natural Science Foundation of China (Nos. 21971117 and 21522106), 111 Project (B18030) from China, the Open Funds (RERU2019001) of the State Key Laboratory of Rare Earth Resource Utilization and the Functional Research Funds for the Central Universities, Nankai University (ZB19500202).application/pdfen-AU© 2020 Wiley-VCH GmbH202010.1002/adfm.2020011272021-08-01