ortho -Metallated triphenylphosphine chalcogenide complexes of platinum and palladium: synthesis and catalytic activity

Priver, Steven HBennett, MartinWillis, AnthonyPottabathula, SrinivasLakshmi Kantam, MannepalliBhargava, Suresh Kumar2015-12-101477-9226http://hdl.handle.net/1885/63544Treatment of [PtI2(COD)] (COD = 1,5-cyclooctadiene) with 2-LiC6H4P(S)Ph2 gives the complex cis-[Pt{κ2-2-C6H4P(S)Ph2} 2] (1) containing a pair of ortho-metallated triphenylphosphine sulfide rings. The selenium counterpart, [Pt{κ2-2-C 6H4P(Se)Ph2}2] (2),ortho -Metallated triphenylphosphine chalcogenide complexes of platinum and palladium: synthesis and catalytic activity201410.1039/c4dt01236d2015-12-10