Synthesis of 1,3-azaphosphol-2-ones. Crystal and molecular structures of [ SP-4-2 ] -dichlorobis(3-phenyl-1,3-dihydrobenzo[1,3]azaphosphol-2-one-P)palladium(II) and its chloro(methyl)platinum(II) analogue

Bennett, JustineDoyle, RoyLee, Hwi-YoungLu, DiSalem, GeoffreySpeldewinde, DavidTifan, MichelleWillis, Anthony2015-12-101477-9226http://hdl.handle.net/1885/58530Reaction of secondary phosphine (±)-(2-aminophenyl)phenylphosphine, (±)-app, with PCl5 in toluene gives the hydrochloride salt of the expected chlorophosphine (±)-(2-aminophenyl)chlorophenylphosphine, (±)-acpp.HCl, however, this is not the case with tKeywords: Benzyl bromide; Benzyl derivatives; Crystal and molecular structure; Hydrochloride salts; Hydrophosphination; Low-yield; Magnesium bromide; Methyl iodide; Phenylphosphines; Secondary phosphines; Synthetic routes; Tertiary phosphines; Triphosgene; HydrocarSynthesis of 1,3-azaphosphol-2-ones. Crystal and molecular structures of [ SP-4-2 ] -dichlorobis(3-phenyl-1,3-dihydrobenzo[1,3]azaphosphol-2-one-P)palladium(II) and its chloro(methyl)platinum(II) analogue201010.1039/b916913j2016-02-24