Bissember, AlexanderBanwell, Martin2015-12-070040-4020http://hdl.handle.net/1885/17097The epimeric forms of the angularly substituted quinolizidine 6, representing potentially useful building blocks for the synthesis of various alkaloids, have been prepared via a pathway involving two consecutive ring-closing metathesis reactions. Variously hydroxy-protected derivatives (21, 22, and 26-29) of these compounds have also been generated.Keywords: alkaloid derivative; quinolizidine derivative; article; chemical analysis; chemical reaction; chemical structure; drug synthesis; priority journal; ring closing metathesis Alkaloids; Fasicularin; Quinolizidines; Ring-closing metathesis; VinylationPreparation of some angularly substituted and highly functionalized quinolizidines as building blocks for the synthesis of various alkaloids and related scaffolds of medicinal interest200910.1016/j.tet.2009.07.0672016-02-24