Depression of reactivity by the collision energy in the single barrier H + CD 4 → HD + CD 3 reaction

Zhang, WeiqingZhou, YongWu, GuorongLu, YunpengPan, HuilinFu, BinaShuai, QuanLiu, LanLiu, ShuZhang, LilingJiang, BoDai, DongxuLee, Soo-YXie, ZengBraams, Bastiaan JBowman, Joel ECollins, MichaelZhang, Dong HuiYang, X2015-12-100027-8424http://hdl.handle.net/1885/60082Crossed molecular beam experiments and accurate quantum scattering calculations have been carried out for the polyatomic H + CD4 → HD + CD3 reaction. Unprecedented agreement has been achieved between theory and experiments on the energy dependence of thKeywords: hydrogen; article; atom; chemical reaction; collision energy; crossed beams scattering technique; energy; mathematical analysis; priority journal; quantum chemistry; technique Chemical reaction dynamics; Cross section; Crossed molecular beam equipment; Potential energy surface; Quantum scatteringDepression of reactivity by the collision energy in the single barrier H + CD 4 → HD + CD 3 reaction201010.1073/pnas.10069101072016-02-24