Reaction of [Fe{C(=O)N′Pr2}(CO)4]- with trifluoroacetic Anhydride: Molecular structure of [Fe(CF3){η2-C(=O)N′Pr2}(CO)2(PPh3)]

Anderson, StephenHill, Anthony F.Clark, George R.2026-01-042026-01-040276-7333ORCID:/0000-0003-2167-0604/work/167652088https://hdl.handle.net/1885/733803627The reactions of the (carbamoyl)tetracarbonylferrate [Fe{C(=O)N′Pr2}(CO)4]- with (CF3CO)2O and PPh3 provide the structurally characterized trlfluoromethyl-carbamoyl complex [Fe(CF3){η2-C(=O)N′Pr2}-(CO)2(PPh3)]. A similar reaction with Ph3SnCl and PPh3 provides the stannyl derivative [Fe(SnPh3) {η2-C(=O)N′Pr2}(CO)2(PPh3)].3enReaction of [Fe{C(=O)N′Pr2}(CO)4]- with trifluoroacetic Anhydride: Molecular structure of [Fe(CF3){η2-C(=O)N′Pr2}(CO)2(PPh3)]1992-06-0110.1021/om00042a0050010924603