Reactivities of amino acid derivatives toward hydrogen abstraction by Cl• and OH•

Date

2012

Authors

Chan, Bun
O'Reilly, Robert J
Easton, Christopher
Radom, Leo

Journal Title

Journal ISSN

Volume Title

Publisher

American Chemical Society

Abstract

In recent computational studies of hydrogen-atom abstraction from amino acid derivatives, two distinct rationalizations have been put forward for the relative inertness of the α-C-H. Of these, the proposal that the inertness is due to a "kinetic trap" as

Description

Keywords

Keywords: Amino acid derivatives; Computational studies; Hydrogen abstraction; Kinetic traps; Polar effect; Stable complexes; Amino acids; Hydrogen; Abstracting; amide; amino acid derivative; chloride; hydrogen; hydroxide; article; chemical interaction; chemical re

Citation

Source

Journal of Organic Chemistry

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

Restricted until

2037-12-31