Spin transition centres linked by the nitroprusside ion. The cooperative transition in bis(2,6-bis(pyrazol-3-yl)pyridine)iron(II) nitroprusside

Date

2003

Authors

Sugiyarto, Kristian
McHale, Wendy-Anne
Craig, Donald C
Rae, A David
Scudder, Marcia
Goodwin, Harold

Journal Title

Journal ISSN

Volume Title

Publisher

Royal Society of Chemistry

Abstract

The complex [Fe(3-bpp)2][Fe(CN)5(NO)] (3-bpp = 2,6-bis(pyrazol-3-yl)pyridine) undergoes an abrupt, thermally-induced 1A1 ↔ 5T2 spin transition associated with a narrow (∼3 K) hysteresis loop (T1/2↓ = 181 K; T1/2 = ↑ 84 K). The transition is accomp

Description

Keywords

Keywords: Crystallography; Electron energy levels; Hydrogen bonds; Hysteresis; Iron compounds; Negative ions; Nitrogen compounds; Positive ions; Complex cations; Hysteresis loops; Nitroprussides; Spin transition; Complexation

Citation

Source

Dalton Transactions

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1039/b301218b

Restricted until

2037-12-31