Mechanical properties of a metal-organic framework containing hydrogen-bonded bifluoride linkers

Date

2013

Authors

Li, Wei
Mangalampalli, S.R.N. Kiran
Manson, Jamie L
Schlueter, John A
Thirumurugan, A
Ramamurty, U
Cheetham, Anthony K

Journal Title

Journal ISSN

Volume Title

Publisher

Royal Society of Chemistry

Abstract

We report the mechanical properties of a framework structure, [Cu 2F(HF)(HF2)(pyz)4][(SbF6) 2]n (pyz = pyrazine), in which [Cu(pyz)2] 2+ layers are pillared by HF2 - anions containing the exceptionally strong F-H⋯F hydrogen bonds. Nanoindentation studie

Description

Keywords

Keywords: fluoride; metal organic framework; pyrazine; anisotropy; article; atomic force microscopy; crystal structure; hardness; hydrogen bond; Young modulus; Copper; Fluorides; Hydrogen Bonding; Organometallic Compounds; Pyrazines

Citation

Source

Chemical Communications

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1039/c3cc41357h

Restricted until

2037-12-31